Synthesis of oligomeric group IVA ferrocene polyesters | Zendy

Carraher Charles E. | Zendy; Jorgensen Steven | Zendy; Lessek Paul J. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of oligomeric group IVA ferrocene polyesters

Author(s) -

Carraher Charles E.,

Jorgensen Steven,

Lessek Paul J.

Publication year - 1976

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.1976.070200821

Subject(s) - substituent , ferrocene , polyester , steric effects , nucleophile , polymer chemistry , yield (engineering) , condensation reaction , materials science , condensation polymer , group (periodic table) , condensation , oligomer , end group , breakage , chemistry , organic chemistry , polymerization , polymer , composite material , catalysis , physics , electrode , electrochemistry , thermodynamics

Oligomeric Group IVA ferrocene Polyesters were synthesized utilizing the interfacial condensation technique. Yield decreases with increasing complexity of the aliphatic substituent; it decreases in the order of I > Br > Cl, and it decreases in the order of Sn > Ge > Si. Thus, initial attack by the nucleophile, steric requirements, and metal—halide bond breakage appear important:Where M = Si, Ge, or Sn.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research