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Reverse osmosis separations of aldehydes, ketones, and ethers in aqueous solutions using porous cellulose acetate membranes
Author(s) -
Matsuura Takeshi,
Bednas M. E.,
Dickson J. M.,
Sourirajan S.
Publication year - 1975
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1975.070190910
Subject(s) - aqueous solution , chemistry , membrane , reverse osmosis , ketone , aldehyde , ether , chromatography , organic chemistry , biochemistry , catalysis
Reverse osmosis data for a number of aldehyde, ketone, and ether solutes whose polar parameters Σσ* lie in the ranges of −0.2 to 0.6, −0.4 to 0.6, and −0.49 to 0.6, respectively, have been analyzed. The results show that solute transport parameters can be expressed as a function of steric parameters Σ E s only for ethers, polar parameter Σσ* only for aldehydes, and both Σ E s and Σσ* for ketones. The numerical values of the functional proportionality constants ρ* and δ* associated with Σσ* and Σ E s respectively, for the above class of solutes have been determined for operating pressures up to 500 psig, and a method of predicting solute separation from data on any reference solute only in each class has been established. The data on solute transport parameters for ethers, aldehydes, and ketones have been correlated with the corresponding data for sodium chloride through appropriate link constants. Analysis of data on mixed solute systems involving aldehydes and ketones show that the solutes behave independently in reverse osmosis.