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The thermal degradation of model compounds of amine‐cured epoxide resins. III. The thermal degradation of 1‐(N‐ethylanilino)‐3‐phenoxyprop‐2‐yl acetate, trifluoroacetate, and methyl ether and O‐deuterated 1‐(N‐ethylanilino)‐3‐phenoxypropan‐2‐ol
Author(s) -
PatersonJones J. C.
Publication year - 1975
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1975.070190207
Subject(s) - epoxide , ether , degradation (telecommunications) , chemistry , amine gas treating , organic chemistry , deuterium , polymer chemistry , nuclear chemistry , catalysis , telecommunications , physics , quantum mechanics , computer science
The thermal degradations of 1‐(N‐ethylanilino)‐3‐phenoxyprop‐2‐yl acetate, trifluroacetate, and methyl ether were studied. Major products were characterized. 1‐(N‐Ethylanilino)‐3‐phenoxypropan‐2‐ol in which the hydroxyl hydrogen was replaced with deuterium was degraded and the extent of deuteration of the one product, N‐ethyl‐N‐methylaniline, was measured by mass spectrometry. The results were used to investigate the mechanism of the thermal degradation of 1‐(N‐ethylanilino)‐3‐phenoxy‐propan‐2‐ol, a model compound for the cure linkage in aromatic amine‐cured epoxide resins.