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Bulk polymerization of vinyl chloride–commercial initiator systems
Author(s) -
AbdelAlim A. H.,
Hamielec A. E.
Publication year - 1974
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1974.070180602
Subject(s) - benzoyl peroxide , polymerization , peroxide , vinyl chloride , polymer chemistry , bulk polymerization , chemistry , polyvinyl chloride , chloride , materials science , radical polymerization , organic chemistry , copolymer , polymer
The applicability of a model after Talamini for the bulk polymerization of vinyl chloride with several commercial initiators has been examined. The model agrees well with experimental rate data for the initiators: diisopropyl peroxydicarbonate, disecbutyl peroxydicarbonate, t ‐butyl peroxypivalate, lauroyl peroxide and benzoyl peroxide.