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The ferric hydroxide/hydrazine system as an initiator of vinyl polymerization
Author(s) -
Brown C. W.,
Longbottom H. M.
Publication year - 1973
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1973.070170611
Subject(s) - hydrazine (antidepressant) , polymerization , hydroxide , metal hydroxide , methyl methacrylate , polymer chemistry , ferric , chemistry , radical polymerization , inorganic chemistry , organic chemistry , polymer , chromatography
The reaction between ferric hydroxide and hydrazine was used to initiate the solution polymerization of methyl methacrylate. Polymerization occurs readily at pH > 6, over a wide range of iron concentration and of temperature. The initiation reaction appears to be of heterogeneous nature, like those in similar metal hydroxide/hydrazine systems.
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