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The stress cracking of polyamides by metal salts. Part II. Mechanism of cracking
Author(s) -
Dunn P.,
Sansom G. F.
Publication year - 1969
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1969.070130807
Subject(s) - chemistry , halide , polyamide , metal halides , amide , metal , polymer chemistry , inorganic chemistry , zinc , organic chemistry
The action of metal halides on polyamide (nylon 6) and secondary amide model compounds has been investigated, using infrared and NMR techniques. Metal halides, which are active stress cracking agents for polyamides, induce characteristic changes in the spectra of both nylon 6 and the model compounds. Two types of changes were observed, depending on the metal halide involved, and on this basis the metal halides have been classified as Type I or Type II. The spectral changes appear to be due to the formation of complexes between the amide group and the metal halide, and structures for these complexes are proposed. Type I metal halides, such as zinc, cobalt II , copper II and manganese II chlorides, form complexes in which the metal atom is coordinately bonded to the carbonyl oxygen atom of the amide group. These agents cause stress cracking by interference with the hydrogen bonding in the polyamide. Type II metal halides, such as lithium, calcium and magnesium chlorides and lithium bromide in solution form proton donating, solvated, species which act as direct solvents for nylon 6 in a manner similar to phenols and formic acid. Type II agents appear to cause simple solvent cracking.