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Effect of lignin in graft copolymerization of methyl methacrylate on cellulose by ceric ion
Author(s) -
Kubota Hitoshi,
Ogiwara Yoshitaka
Publication year - 1969
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1969.070130719
Subject(s) - lignin , copolymer , cellulose , methyl methacrylate , pulp (tooth) , grafting , polymer chemistry , chemistry , polymer , materials science , organic chemistry , medicine , pathology
The effect of lignin contained in cellulosic materials in graft copolymerization of methyl methacrylate on such materials using ceric ion as initiator was studied. It was found that the percent grafting and the average molecular weight of grafts became lower in samples having a larger lignin content but the number of grafts formed increased proportionally up to lignin content of about 2.5%. Ceric ion reacted at a faster rate with lignin than with cellulose in wood pulp, and the results indicating that the active sites formed on lignin by oxidation with ceric ion accelerate the formation of grafts and increase the number of grafts were obtained. But on the other hand, the active sites participated in the termination reaction of the growing graft polymer radicals to cause lowering of the average molecular weight of grafts.