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Nitrogen‐containing monomers. III. Reactivity ratios of N ‐alkyl acrylamides with vinyl monomers
Author(s) -
Bork John F.,
Wyman D. P.,
Coleman L. E.
Publication year - 1963
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1963.070070204
Subject(s) - acrylamide , reactivity (psychology) , monomer , styrene , methyl methacrylate , polymer chemistry , chemistry , methacrylate , alkyl , organic chemistry , polymer , copolymer , medicine , alternative medicine , pathology
The reactivity ratios in the copolymerizations of N ‐ tert ‐octyl acrylamide, N ‐ n ‐octyl acrylamide, and N , N ‐di‐ n ‐butyl acrylamide with styrene and methyl methacrylate have been determined, and the Alfrey‐Price Q and e values calculated. The distributed monomer N , N ‐di‐ n ‐butyl acrylamide was found to be more reactive than either N ‐ n ‐octyl or N ‐ tert ‐octyl acrylamide, which were of about the same reactivity.