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Mullins effect and rubber–filler interaction
Author(s) -
Bueche F.
Publication year - 1961
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1961.070051504
Subject(s) - natural rubber , materials science , composite material , filler (materials) , carbon black , compression set , ultimate tensile strength , styrene butadiene , polymer , stress (linguistics) , styrene , copolymer , linguistics , philosophy
A previously reported theory for the Mullins softening effect has been used to interpret various new data for the behavior of filled SBR rubber under tensile load. The strength of the filler–rubber bond, the filler surface area per polymer molecule attachment, and the average filler surface separation have been determined for two fillers, HAF black and Hi Sil‐233 (a silica). A styrene–butadiene type filler (Pliolite S‐6) has also been investigated. The temperature dependence of the filler–rubber bond has been measured; results lead to the conclusion that the bonds to carbon black and silica are high energy bonds, probably chemical in nature. It is shown that the recovery of hardness in prestretched, filled SBR is a rate process having an activation energy of about 22 kcal./mole. It is inferred from this and from permanent set data that the recovery is the result of the chemical breaking and reforming of the rubber chain network at the higher temperatures where recovery occurs. Silica‐filled rubbers are shown to possess a pseudoyield stress which gives rise to an anomalous shape for the stress–strain curve of this material when it is stretched for the first time. A prestretched, silica‐filled rubber recovers its hardness when left at 115°C. for 20 hr., but the anomalous portion of the curve is replaced by more normal behavior. Possible interpretations of the observed results are given.