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Temperature dependence of dynamic mechanical properties of mixed polymer systems
Author(s) -
McIntyre A. D.
Publication year - 1961
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1961.070051411
Subject(s) - copolymer , styrene , materials science , glass transition , polymer , styrene butadiene , polymer chemistry , mole fraction , dynamic mechanical analysis , atmospheric temperature range , homologous series , thermodynamics , composite material , chemistry , organic chemistry , physics
The temperature dependence of the viscous component E 2 (1/ T ) of the dynamic modulus is reported for a homologous series of butadiene–styrene copolymers incorporated at various levels in styrene homopolymer. By the use of a vibrating reed technique based on resonance tuning, the frequency of the applied deformation was maintained essentially constant throughout the temperature range which included the glass transitions of the copolymers. It is shown that, when E 2 (1/ T ) for such mixed polymer systems is plotted against reciprocal absolute temperature, the area under the peak corresponding to a given copolymer affords a direct measure of the quantity of the copolymer present. Further, the temperature of maximum E 2 (1/ T ) is related to the mole fraction of bound styrene in the copolymer, and the shape of the peak is related to the statistical sequence lengths of styrene and butadiene in the copolymer.