Copolymerization behavior of 3‐isopropenyl‐α,α‐dimethylbenzylamine and a preliminary evaluation of the copolymers in thermoset coatings | Zendy

Trumbo D. L. | Zendy; Mote B. E. | Zendy; Trevino A. S. | Zendy; van den Brink M. | Zendy

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Copolymerization behavior of 3‐isopropenyl‐α,α‐dimethylbenzylamine and a preliminary evaluation of the copolymers in thermoset coatings

Author(s) -

Trumbo D. L.,

Mote B. E.,

Trevino A. S.,

van den Brink M.

Publication year - 2001

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.1937

Subject(s) - copolymer , thermosetting polymer , monomer , polymer chemistry , isocyanate , materials science , epoxy , solvent , gloss (optics) , yield (engineering) , chemistry , polyurethane , organic chemistry , polymer , composite material , coating

The title monomer was synthesized from 3‐isopropenyl‐α,α‐dimethylbenzyl isocyanate in a significantly better yield than was previously reported. 3‐Isopropenyl‐α,α‐dimethylbenzylamine proved incapable of homopolymerization using free‐radical initiation but readily copolymerized with a variety of commonly available monomers under free‐radical conditions. Films of some of the copolymers were prepared and crosslinked using a variety of multifunctional epoxy compounds. The films had good solvent resistance, high hardness, and good gloss. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 1030–1039;2001

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