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Synthesis and the magnetic properties of novel metal(II) complexes of polyamides
Author(s) -
Liu Jiageng,
Sun Weilin,
Lu Fengcai
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1911
Subject(s) - polyamide , metal , polymer chemistry , electron paramagnetic resonance , materials science , magnetization , chemistry , nuclear magnetic resonance , physics , magnetic field , metallurgy , quantum mechanics
Novel polyamides DTPA and DTPyA are prepared from 2,2′‐diamino‐4,4′‐bisthiazole and aromatic polycarbonyl chloride. The complexes of Fe(II) and Cu(II) metal of the polyamides are also prepared. The complexes as well as the polyamides are characterized through IR and EPR, and the magnetic property of each complex are measured through MPMS. It is found the Fe(II) complexes of both DTPA and DTPyA reveal magnetization ability, especially the Fe(II) DTPA complex. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 818–822, 2001