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Synthesis, characterization, and electrical conductivity of polyaniline derivatives: Study with the metal ions Cu(II), Ni(II), and Co(II)
Author(s) -
Rivas B. L.,
Sánchez C. O.
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1856
Subject(s) - aniline , oxidizing agent , polymerization , metal ions in aqueous solution , ammonium persulfate , metal , polymer chemistry , chemistry , polyaniline , inorganic chemistry , thermal stability , reagent , fourier transform infrared spectroscopy , materials science , polymer , organic chemistry , chemical engineering , engineering
Abstract Poly(2‐aminophenol), poly(3‐aminophenol), poly(2‐aminobenzyl alcohol), and poly(3‐aminobenzyl alcohol) were synthesized by using ammonium persulphate as oxidizing reagent in HCl and HCl/CH 3 CN mediums in the presence and absence of Cu(II), Ni(II), and Co(II) ions. The polymers were characterized by Fourier transform infrared spectroscopy, ultraviolet‐vis spectroscopy, thermal analysis, and electrical conductivity measurements. The substituent in 2‐ and 3‐positions decreases the yield regarding aniline. Poly(2‐,3‐aminobenzyl alcohol) are obtained in an intermediate redox state and polymerized as aniline. On the contrary, poly(aminophenols) are obtained as overoxidated structures. The presence of metal ion produces an important increase of the polymerization yield. The metal cations would act as oxidizing agents. The incorporation of these metal ions depends on the reaction medium. The metal ion increases the thermal stability. Poly(2‐aminobenzyl alcohol)‐copper ions also increases the electrical conductivity. The electrical conductivity is higher by acid doping than by the incorporation of metal ions. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 330–337, 2001