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Study of ethylene polymerization catalyzed by nBu‐Cp 2 ZrCl 2 /MAO catalytic system and their polymerization kinetics
Author(s) -
Wang L.,
Zhang P. Y.,
Jiang S.,
Feng L. X.
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1771
Subject(s) - polymerization , polyethylene , kinetics , catalysis , ethylene , polymer chemistry , chemistry , organic chemistry , polymer , physics , quantum mechanics
Polyethylene was prepared by using a nBu‐Cp 2 ZrCl 2 /MAO catalytic system. Considering the reactivation of Zr species, a novel and reasonable mathematical model of kinetics has been developed and the kinetic profiles of ethylene polymerization have been fitted satisfactorily. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 3186–3189, 2001