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Temperature and atmosphere influences on smoke composition during thermal degradation of poly(ethylene terephthalate)
Author(s) -
Dziȩcioł Małgorzata,
Trzeszczyński Jerzy
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1757
Subject(s) - degradation (telecommunications) , ethylene , materials science , smoke , atmosphere (unit) , gas chromatography , chemical engineering , thermal , analytical chemistry (journal) , chemistry , chromatography , organic chemistry , catalysis , thermodynamics , telecommunications , physics , computer science , engineering
Abstract The less‐volatile compounds forming a smoke emitted during the thermal degradation of poly(ethylene terephthalate) (PET) in different conditions were studied. Thermal degradation of PET was carried out within the temperature range of 200–700°C in both a nitrogen and an air atmosphere. The less‐volatile thermal degradation products were trapped on a glass‐fiber filter and analyzed by capillary gas chromatography with mass selective detector (GC‐MS) and high performance liquid chromatography (HPLC). The results are collected in tables and presented on plots as a function of the degradation temperature. The temperature and atmosphere effects on the emission and composition of the smoke during PET thermal degradation were considered. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 3064–3068, 2001