Premium
Molecular weight and distribution of copolymer of lignin‐phenol in copolymerization catalyzed by peroxidase
Author(s) -
Liu Junhong,
Li Liangzhi,
Cheng Jiangfeng,
Wang Lixin,
Ye Lin
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1681
Subject(s) - copolymer , molar mass distribution , phenol , polymer chemistry , lignin , pulmonary surfactant , polymer , catalysis , materials science , thermal stability , chemistry , organic chemistry , biochemistry
The molecular weight and distribution of lignin‐cresol polymer in peroxidase‐catalyzed copolymerization of lignin with cresol in the reversed micellar system can be controlled by adjusting the surfactant concentration and other factors. The maximal mean molecular weight of copolymer obtained is 1890 kDa. The surfactant sustains chain growth. The cresol and/or polycresol is incorporated into the copolymer, and the thermal property of the copolymer is improved. A correlation for copolymer mean molecular weight is developed. The synthesized copolymer drops out of solution and can be easily recovered. The materials appear to act as thermosets and may have applications as replacements of conventional phenolic resins. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 2408–2418, 2001