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Poly(styrene‐ alt ‐maleic acid)–metal complexes with divalent metal ions. synthesis, characterization, and physical properties
Author(s) -
Rivas Bernabé L.,
Seguel Gloria V.,
Geckeler Kurt E.
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1555
Subject(s) - thermogravimetry , maleic acid , styrene , copolymer , metal , polymer chemistry , materials science , characterization (materials science) , metal ions in aqueous solution , polymer , conductivity , divalent , chemistry , inorganic chemistry , composite material , nanotechnology , metallurgy
Abstract Polymer–metal complexes of the alternating copolymer styrene and maleic acid with Cu(II), Co(II), Ni(II), and Zn(II) were synthesized and characterized by elemental analysis, infrarred and electronic spectra, and thermogravimetry. In addition, magnetic measurements were performed and the electrical conductivity was studied at different temperatures. Semiempirical calculations at the PM 3 level were carried out to elucidate the geometrical arrangement of the polychelates. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1310–1315, 2001