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Preparation of poly(vinyl butyral) with high acetalization rate
Author(s) -
Chetri P.,
Dass N. N.
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1540
Subject(s) - vinyl alcohol , thermogravimetric analysis , differential scanning calorimetry , polymer chemistry , thermogravimetry , thermal decomposition , acetal , catalysis , polymer , chemistry , materials science , nuclear chemistry , organic chemistry , inorganic chemistry , thermodynamics , physics
Poly(vinyl alcohol) (PVA) can be dissolved in a nonaqueous medium in the presence of catalytic concentration of ethyl nitrate dimethyl sulfoxide, C 2 H 5 ONO 2 · DMSO (EN · DMSO). From the PVA solution, poly(vinyl butyral) (PVBu) was prepared by acid‐catalyzed homogeneous acetalization of PVA with butyraldehyde. The formation of PVBu was confirmed by IR and 1 H‐NMR spectra. The degree of acetalization of PVBu was found to be 95 mol %, which was verified by 1 H‐NMR data and acetylation method. The molecular mass of the polymer was determined by GPC method. The glass transition temperature, T g , was measured from differential scanning calorimetric (DSC) thermograms. Thermal stabilities were checked by thermogravimetric analysis (TGA) and differential thermogravimetry (DTG). The acetal decomposed in three stages. The corresponding initial decomposition temperatures were found to be 285, 390, and above 500°C. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1182–1186, 2001