New postfunctional method to synthesize C 60 ‐containing poly(ethylene oxide) | Zendy

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New postfunctional method to synthesize C 60 ‐containing poly(ethylene oxide)

Author(s) -

Li Zhen,

Shao Pin,

Qin Jingui

Publication year - 2004

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.13695

Subject(s) - ethylene oxide , chlorobenzene , polymer , ethylene , oxide , polymer chemistry , solubility , molecule , materials science , yield (engineering) , macromolecule , poly ethylene , chemistry , organic chemistry , copolymer , catalysis , metallurgy , biochemistry

This article reports the detailed synthesis and structural characterization of two new C 60 ‐containing poly(ethylene oxide)s by a new postfunctional method. A predesigned amino end‐functionalized poly(ethylene oxide) was prepared, and this reactive macromolecular intermediate was reacted with C 60 molecules in chlorobenzene to yield the C 60 ‐containing poly(ethylene oxide)s. The molecular structures of the polymers were characterized with 1 H‐NMR, IR, and ultraviolet–visible spectra. The polymers exhibited good solubility in common organic solvents and water and were stable in air. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 867–870, 2004

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