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Synthesis and characterization of poly( o ‐ and m ‐amino benzyl amine) and the copolymers with aniline. Study with Cu(II)
Author(s) -
Rivas Bernabé L.,
Sánchez Christian O.
Publication year - 2004
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.13630
Subject(s) - aniline , polymer chemistry , copolymer , comonomer , ammonium persulfate , amine gas treating , diamine , polymerization , thermal stability , chemistry , materials science , polymer , organic chemistry
Poly( o ‐amino benzyl amine), poly( m ‐amino benzyl amine), and the copolymers with aniline were synthesized in 10 −4 M HCl by using ammonium persulfate as oxidizing agent. The copolymers were synthesized at various feed mole fractions of comonomer diamine and characterized by elemental analysis, FTIR, 1 H‐NMR spectroscopy, and electrical conductivity. The polymerization yield depended on the substituent position in the aromatic ring. Copper ion was incorporated in the polymers and the amount depended on the side groups position in the aromatic ring. The thermal stability increased when copper ions and aniline units were incorporated in the polymers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 31–36, 2004