Premium
Preparation of thermoplastic elastomers based on silicone rubber and polyethylene by thermomechanical reactive blending: Effects of polyethylene structural parameters
Author(s) -
JalaliArani A.,
Katbab A. A.,
Nazockdast H.
Publication year - 2003
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.13064
Subject(s) - materials science , linear low density polyethylene , vulcanization , polyethylene , thermoplastic elastomer , composite material , compatibilization , elastomer , rheology , silicone , natural rubber , rheometry , mooney viscosity , silicone rubber , dynamic mechanical analysis , polymer blend , polymer , copolymer
Attempts have been made to prepare thermoplastic elastomers based on polyethylene and silicone rubber by thermomechanical reactive mixing of the two polymers. Occurrence of both grafting and vulcanization of the silicone rubber chains was evidenced by increase in the mixing torque, solvent extraction data, as well as FTIR and DSC analysis. Among different types of polyethylene, linear low‐density polyethylene (LLDPE) showed higher potential to promote reactions between the two phases. The blend based on LLDPE prepared at high temperature and shear rate exhibited distinct rheological behavior with a non‐Newtonian characteristic and higher dynamic viscosity measured by rheomechanical spectroscopy (RMS) than the two individual components at low frequencies. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3402–3408, 2003