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Mesomorphic properties of cholesteric side‐chain liquid crystalline polysiloxanes and elastomers
Author(s) -
Liu LuMei,
Zhang BaoYan,
Cheng ChunSheng,
Zheng YingYing
Publication year - 2003
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.13041
Subject(s) - thermotropic crystal , polymer , materials science , differential scanning calorimetry , polymer chemistry , elastomer , copolymer , liquid crystalline , side chain , chemical engineering , composite material , thermodynamics , physics , engineering
A series of crosslinked liquid crystalline polymers and corresponding uncrosslinked liquid crystalline polymers were prepared by graft copolymerization. Their liquid crystalline properties were characterized by differential scanning calorimetry, polarizing optical microscopy, and X‐ray diffraction measurements. The results showed that the crosslinking obtained in the isotropic state and the introduction of nonmesogenic crosslinking units into a polymeric structure could cause additional reduction of the clearing point ( T i ) of the crosslinked polymers, compared with the corresponding uncrosslinked polymers. The crosslinked polymers (P‐2–P‐4) with a low crosslinking density exhibited cholesteric phases as did the uncrosslinked polymers. In contrast, a high crosslinking density made the crosslinked polymer P‐5 lose its thermotropic liquid crystalline property. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 773–778, 2004