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Premium Photon transmission technique for monitoring drying processes in acrylamide gels formed with various crosslinker contents
Author(s)
Kara Selim,
Pekcan Önder
Publication year2001
Publication title
journal of applied polymer science
Resource typeJournals
PublisherJohn Wiley & Sons
Abstract In situ photon transmission experiments were performed using UV‐visible (UVV) spectrometer during the drying of polyacrylamide (PAAm) gels. These gels are formed from acrylamide (AAm) with various N,N ′‐methylenebis(acrylamide) (Bis) contents by free radical crosslinking copolymerization (FCC) in water. The transmitted light intensity, I tr increased continuously as PAAm gels are dried. Increase in I tr was attributed to the decrease in the scattered light intensity, I sc , which might be originated from the contrast between “frozen blob clusters” and holes in the drying gel. Decrease in I sc was modeled using Rayleigh's equation, where drying times with various exponents were found to be proportional to the volume of frozen blob clusters. It was observed that the radius of frozen blob cluster (correlation length), ξ c increased in various power of time, depending on Bis contents during drying of gels. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 1898–1906, 2001
Subject(s)acrylamide , analytical chemistry (journal) , chemistry , chromatography , composite material , computer science , computer security , copolymer , intensity (physics) , materials science , optics , physics , polyacrylamide , polymer , polymer chemistry , radius
Language(s)English
SCImago Journal Rank0.575
H-Index166
eISSN1097-4628
pISSN0021-8995
DOI10.1002/app.1287

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