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Effect of inorganic salts on viscosity of acrylonitrile‐ N ‐vinylpyrrolidone copolymer solutions
Author(s) -
Hou Chen,
Wang ChengGuo,
Ying Liang,
Cai HuaSu
Publication year - 2003
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.12501
Subject(s) - acrylonitrile , copolymer , viscosity , viscometer , reduced viscosity , polymer chemistry , intrinsic viscosity , chemistry , relative viscosity , materials science , chemical engineering , polymer , organic chemistry , composite material , engineering
Effects of inorganic salts on viscosities of dimethyl sulphoxide (DMSO) solutions of acrylonitrile(AN)/ N ‐vinylpyrrolidone( N ‐VP) copolymer are discussed. Viscosity was determined by the rotary viscosimeter. It was shown that the solution viscosity decreases quickly with addition of KCl and NaCl and the effect of NaCl is more prominent than that of KCl. As concentration of KCl and NaCl went beyond 0.025 mol/L, the viscosity showed a trend of increase. The viscosity increased considerably with addition of FeCl 3 and CuCl 2 . Changes in solution viscosity became less obvious with addition of ZnCl 2 . As temperature increased, the viscosity of the copolymer solution containing NaCl decreased most quickly and the copolymer solution consisting of FeCl 3 showed the slowest decrease. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3492–3495, 2003