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A new postfunctional method to synthesize C 60 ‐containing polysiloxanes
Author(s) -
Li Zhen,
Qin Jingui
Publication year - 2003
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.12304
Subject(s) - chlorobenzene , polymer , solubility , yield (engineering) , polymer chemistry , molecule , materials science , macromolecule , characterization (materials science) , ultraviolet , chemistry , chemical engineering , organic chemistry , nanotechnology , catalysis , composite material , biochemistry , optoelectronics , engineering
Two new C 60 ‐containing polysiloxanes were synthesized by a new postfunctional method. First, the predesigned amimo end‐functionalized polysiloxane was prepared, and then the reactive macromolecular intermediate reacted with C 60 molecules in chlorobenzene to yield the C 60 ‐containing polysiloxanes. Molecular structural characterization for the polymers was presented by 1 H‐NMR, IR, and ultraviolet‐visible spectra. The polymers exhibited good solubility in common organic solvents and were air stable. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2068–2071, 2003
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