Premium
Miscibility behavior and coil overlap in ionic blends of phenylated polytriphenylene oxide and poly(methyl methacrylate)
Author(s) -
Rajagopalan M.,
Natansohn A.,
Eisenberg A.,
Tannenbaum R.
Publication year - 2003
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.12197
Subject(s) - miscibility , materials science , polymer chemistry , methyl methacrylate , oxide , methacrylate , proton nmr , ionic bonding , ethylene oxide , polymer , copolymer , chemistry , organic chemistry , composite material , ion , metallurgy
Blends of sulfonated phenylated polytriphenylene oxide and poly(methyl methacrylate‐ co ‐4‐vinyl pyridine) were examined by dynamic mechanical, Fourier transform infrared, and NMR techniques. A high degree of miscibility was evident from a single drop in a plot of the storage modulus versus the temperature. The presence of ionic moieties due to proton transfer from sulfonic acid to 4‐vinyl pyridine was confirmed by both NMR and IR spectroscopy studies. The coils were found to be close to one another in dimethyl sulfoxide‐ d 6 because the aromatic shielding effect of the phenyl rings of the phenylated polytriphenylene oxide units was observed from the upfield shift of most of the protons of poly(methyl methacrylate) in the NMR spectrum. However, the absence of cross peaks in the nuclear Overhauser and exchange spectroscopy experiments suggested that the intermolecular distance between the chains had to be larger than 4 Å. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 728–733, 2003