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Pervaporation separation of water and dioxane mixtures with sodium alginate‐ g ‐polyacrylamide copolymeric membranes
Author(s) -
Kurkuri Mahaveer D.,
Aminabhavi Tejraj M.
Publication year - 2003
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.12087
Subject(s) - pervaporation , membrane , permeation , polymer chemistry , chemical engineering , polyacrylamide , vinyl alcohol , chemistry , swelling , diffusion , materials science , chromatography , polymer , organic chemistry , thermodynamics , biochemistry , engineering , physics
Polyacrylamide (pAAm)‐ grafted sodium alginate (NaAlg) copolymeric membranes have been prepared and used in the pervaporation separation of dioxane mixtures containing10–70 mass % water. Three different polymeric membranes have been prepared: neat NaAlg, 46% grafted pAAm‐ g ‐NaAlg, and 93% grafted pAAm‐ g ‐NaAlg. For reduced brittleness and increased flexibility of the membranes, 10 mass % poly(ethylene glycol) and 5 mass % poly(vinyl alcohol) were added to all three membranes. With the transport data for the mixtures through the membranes, the permeation flux, selectivity, pervaporation separation index, swelling index, and diffusion coefficients have been calculated at 30°C. The Arrhenius activation parameters for the transport processes have been calculated for 10 mass % water in the feed mixture with flux and diffusion data obtained at 30, 40, and 50°C. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 300–305, 2003