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Relationship between thermodynamical parameters of activated complexes and initial reactants in the reaction of peroxides with amines
Author(s) -
Turovskiy A. A.,
Turovskiy N. A.,
Kopylets V. I.,
Zagladko E. A.,
Zaikov G. A.
Publication year - 2002
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.11326
Subject(s) - chemistry , thermodynamics , activated complex , standard enthalpy of reaction , polymer chemistry , enthalpy , kinetics , reaction rate constant , physics , quantum mechanics
The linear dependence between heats of formation and entropies of initial reactants on the one hand and the corresponding thermodynamical parameters of activated complexes on the other hand was obtained for the reaction of peroxides with amines. This relationship allows one to estimate such parameters for other similar reactions of amines with peroxides. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 641–642, 2003