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Study on ESR spectra of poly(ferrocenyldimethylsilane)/TCNE and spin‐probed poly(ferrocenyldimethylsilane)
Author(s) -
Wang L.,
Wang X. J.,
Pan J.,
Feng L. X.
Publication year - 2002
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.11085
Subject(s) - tetracyanoethylene , polymer , polymer chemistry , materials science , spin probe , molecular mass , spectral line , electron paramagnetic resonance , chemistry , nuclear magnetic resonance , photochemistry , physics , organic chemistry , composite material , enzyme , astronomy
Poly(ferrocenyldimethylsilanes) with different molecular weights, especially with high molecular weight, have been synthesized. It is found by using the ESR technique that the formation of charge transfer complexes (CTC) between poly(ferrocenyldimethylsilanes) with different molecular weights and tetracyanoethylene (TCNE) is possible. Using 2,2,6,6‐Tetramethyl‐piperidone‐1 as a spin probe, the segment motion of resultant polymers was investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3508–3511, 2002