Synthesis of ultraviolet‐curable modified polysiloxane and its surface properties | Zendy

Tan Bien | Zendy; Pan Huiming | Zendy; Irshad Hussain | Zendy; Chen Xiaohui | Zendy

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Synthesis of ultraviolet‐curable modified polysiloxane and its surface properties

Author(s) -

Tan Bien,

Pan Huiming,

Irshad Hussain,

Chen Xiaohui

Publication year - 2002

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.11005

Subject(s) - octamethylcyclotetrasiloxane , monomer , adhesive , ultraviolet , materials science , adhesion , polymer chemistry , dispersion (optics) , composite material , surface energy , photoinitiator , telomerization , chemical engineering , chemistry , organic chemistry , polymer , catalysis , optics , physics , optoelectronics , layer (electronics) , engineering

A novel ultraviolet (UV)‐curable monomer α,ω‐dichloropolysiloxane was synthesized by the telomerization of dichlorodimethylsilane and octamethylcyclotetrasiloxane (D 4 ). The products with very low peel strength (<0.332 N/cm) could be used as release agents in pressure‐sensitive adhesives. Moreover, the values of the dispersion component of surface energy (γ s d ) from the films of UV‐curable prepolymers (26.40–33.75 mJ/m 2 ) were determined and the effects of γ s don the reduction of adhesion were investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2135–2139, 2002

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