Synthesis, characterization, and chelating properties of the polymacromonomer: Poly[(ethyleneglycol) methyl ether methacrylate] | Zendy

Amalia Pooley S. | Zendy; Rivas Bernabé L. | Zendy; Maureira Antonio E. | Zendy

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Synthesis, characterization, and chelating properties of the polymacromonomer: Poly[(ethyleneglycol) methyl ether methacrylate]

Author(s) -

Amalia Pooley S.,

Rivas Bernabé L.,

Maureira Antonio E.

Publication year - 2002

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.10861

Subject(s) - polymer chemistry , ammonium persulfate , gel permeation chromatography , dispersity , macromonomer , materials science , thermal stability , metal ions in aqueous solution , ether , polymerization , polymer , methyl methacrylate , methacrylate , fourier transform infrared spectroscopy , nuclear chemistry , metal , chemistry , organic chemistry , chemical engineering , metallurgy , composite material , engineering

The radical polymerization of the macromonomer poly(ethyleneglycol) methyl ether methacrylate with ammonium persulfate at 60°C was carried out. The polymer was completely soluble in water. Yield was 75%. The polymacromonomer was characterized by Fourier transform infrared, proton nuclear magnetic resonance (NMR), and 13 C NMR spectroscopy. M n , M w , and the polydispersity were determined by gel permeation chromatography. The polymacromonomer showed a high thermal stability with a TDT 50% of 420°C. The metal ion binding capacity of this polychelatogen with respect to different metal ions was investigated through the liquid‐phase polymer‐based retention (LPR) technique. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2929–2934, 2002

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