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Studies on self‐assembly and characterization of polyelectrolytes and organic dyes
Author(s) -
Lin Xianjun,
Zhong Anyong,
Chen Deben,
Zhou Zonghua,
He Bobing
Publication year - 2002
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.10600
Subject(s) - polyelectrolyte , chemistry , polymer chemistry , methyl orange , fourier transform infrared spectroscopy , fluorescence , methacrylate , alcohol , polymer , chemical engineering , organic chemistry , copolymer , physics , photocatalysis , quantum mechanics , engineering , catalysis
Four polyelectrolyte complexes were formed through the self‐assembly of poly‐N‐ethyl‐N,N‐ dimethylamino ethyl methacrylate (PEDEM) and poly‐ N‐ethyl‐4‐vinylpyridinium (PEVP) cations with methyl orange (MO) and metanil yellow (MY) anions in water. The FTIR spectra showed that the assembly was formed chiefly through electrostatic force and hydrophobic interaction between polyelectrolytes and organic dyes without new bonds emerging. The fluorescence spectra revealed that the emission waves of the complexes of PEDEM‐MY and PEDEM‐MO in alcohol were blue‐shift in comparison with those of dyes in alcohol, and the emission waves of the PEVP‐MY and PEVP‐MO complexes in alcohol were red‐shift in comparison with those of dyes in alcohol. The structure of the complexes in solid state were also investigated by differential thermal analysis (DTA) and X‐ray diffraction experiments. It was proved that the complexes were new materials formed through weak interactions. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 638–644, 2002