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Structure and thermal behavior of nylon‐6/polytetrahydrofuran triblock copolymers obtained via anionic polymerization
Author(s) -
Petrov P.,
Mateva R.,
Dimitrov R.,
Rousseva S.,
Velichkova R.,
Bourssukova M.
Publication year - 2002
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.10448
Subject(s) - copolymer , materials science , crystallinity , dynamic mechanical analysis , glass transition , differential scanning calorimetry , nylon 6 , polymer chemistry , polymerization , thermal stability , ultimate tensile strength , crystallization , polymer , chemical engineering , composite material , physics , engineering , thermodynamics
The structure, crystallization, and phase behavior of nylon6‐ b ‐polytetrahydrofuran‐ b ‐nylon6 triblock copolymers synthesized via activated anionic polymerization have been studied. The composition, molecular weight of polytetrahydrofuran (PTHF) soft block, and type of polymeric activators (PACs) have been varied. Differential Scanning Calorimetry (DSC), Wide‐Angle X‐ray Diffraction (WAXD), Transmission Electron Microscopy (TEM), and Polarized Light Microscopy (PLM) experiments have revealed that in triblock copolymers only the nylon‐6 component crystallizes while PTHF segments are amorphous. The soft blocks do not alter the spherulitic crystalline structure of nylon‐6 and hard blocks crystallize in the α‐modification. The degree of crystallinity decreases with increasing PTHF concentration. The phase behavior has been investigated by Dynamic Mechanical Thermal Analysis (DMTA). Two different glass transition temperatures ( T g ) for all samples have been observed. This indicates that nylon‐6 and PTHF segments are not molecularly miscible and the copolymers are microphase separated. The mechanical properties of the copolymers synthesized have been evaluated. Nylon‐6 copolymers with soft block concentrations up to 10 w/w %, exhibit improved notched impact strength in comparison to the nylon‐6 homopolymer, retaining relatively high hardness and tensile strength. All copolymers possess low water absorption and good thermal stability. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1448–1456, 2002; DOI 10.1002/app.10448