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Thermosetting polyurethanes with water‐swollen and shape memory properties
Author(s) -
Chen Wei,
Zhu Chengye,
Gu Xuerong
Publication year - 2002
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.10357
Subject(s) - materials science , dynamic mechanical analysis , peg ratio , thermosetting polymer , shape memory alloy , small angle x ray scattering , polymerization , morphology (biology) , polyurethane , composite material , chemical engineering , polymer chemistry , polymer , scattering , physics , finance , biology , optics , economics , genetics , engineering
A series of shape memory polyurethanes (SPU) with different component ratio of PEG, MDI, BDO, and crosslinker DEA were synthesized by stepwise polymerization in DMF. WAXD, SAXS, DMTA, and DTA were used to study the microphase structure of SPU. No obvious phase‐separation and crystalline evidence of the PEG soft segment and hard segment were obtained in this work. The water‐swollen ratio increases with both the increasing molecular weight of PEG soft segment and the decreasing density of the chemical crossbonding. All the samples show good thermally stimulated shape memory properties. When the molar ratio of soft segment to hard segment is close, the shape recovery time reduces along with the increasing density of the chemical crossbonding. When the densities of the chemical crossbonding are similar, the shape recovery time reduces with the increasing molecular weight of the PEG soft segment. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1504–1512, 2002; DOI 10.1002/app.10357