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Syntheses and properties of carboxymethyl chitosan/urea–formaldehyde snake‐cage resins
Author(s) -
Qu Rongjun,
Sun Yanzhi,
Wang Chunhua,
Lu Shulai,
Yu Huimei,
Cheng Guoxiang
Publication year - 2002
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.10331
Subject(s) - sorption , urea formaldehyde , polymer chemistry , freundlich equation , aqueous solution , chitosan , langmuir , formaldehyde , swelling , urea , chemistry , nuclear chemistry , materials science , adsorption , organic chemistry , composite material , adhesive , layer (electronics)
A series of novel snake‐cage resins were synthesized using carboxymethyl chitosan (CM‐CTS) as the snake resin and urea–formaldehyde resin (UF) as the cage resin. Such factors as the optimal synthesis conditions, content of the crosslinking agent, and sorption capacities for metal ions of the above‐mentioned resins were investigated. The experimental results show that these resins have appropriate swelling properties and good mechanical stability. They do not run off in water, HCl, and NaOH aqueous solutions. To form a stable network system, NH 4 Cl was used as a crosslinking agent to crosslink urea and formaldehyde in synthesis. The sorption experiment showed that the sorption properties of the resins in the presence of the crosslinking agent NH 4 Cl are better than those without a crosslinking agent. The investigation of the FTIR spectra indicated that the chelate groups, such as —OH, —CO − 2and NHCH 2 CO − 2 , in snake‐resin molecules participated in the coordination with the metal ions, but the —CO bonds in the cage resin UF did not. The snake resin CM‐CTS in the snake‐cage resins was the major contributor of sorption. The sorption dynamics showed that the sorption was controlled by liquid film diffusion. The isotherms can be described by Freundlich and Langmuir equations. The saturated sorption capacities of the resins for Cu 2+ , Ni 2+ , Zn 2+ , and Pb 2+ were 1.48, 0.78, 0.13, and 0.02 mmol g −1 , respectively. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 310–317, 2002; DOI 10.1002/app.10331