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Gas/Liquid Mass Transfer in Hot Sparged Systems
Author(s) -
Zhu Y.,
Wu J.
Publication year - 2004
Publication title -
developments in chemical engineering and mineral processing
Language(s) - English
Resource type - Journals
eISSN - 1932-2143
pISSN - 0969-1855
DOI - 10.1002/apj.5500120408
Subject(s) - sparging , mass transfer , oxygen , analytical chemistry (journal) , impeller , materials science , liquid oxygen , drop (telecommunication) , void (composites) , chemistry , mixing (physics) , limiting oxygen concentration , atmospheric pressure , thermodynamics , chemical engineering , chromatography , composite material , meteorology , telecommunications , physics , organic chemistry , quantum mechanics , computer science , engineering
Understanding the effect of temperature on the volumetric mass transfer rate is of vital importance for the design of chemical reactors operated at elevated temperatures. The present study is motivated by a poor understanding of this effect due to previous limited investigations. Such an effect has been studied at the CSIRO Energy & Thermofluids Engineering Laboratory in a mechanically agitated air‐water mixing tank with operating temperatures in the range of 20‐80d̀C at atmospheric pressure. The oxygen concentration of the liquid is measured by a dissolved oxygen probe. The volumetric mass transfer rate is estimated using a dynamic method. It has been found that the saturated oxygen concentration of the liquid does not change significantly with the gas sparging rate and impeller speed. The change of temperature affects the saturated oxygen concentration significantly. The volumetric mass transfer rate increases with the increase of liquid temperature in the range of 18‐60d̀C. Beyond 60d̀C, the transfer rate decreases. Such a decrease is mainly due to the dramatic drop in the gas void fraction.

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