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Effect of hydrogen on the synthesis of carbon nanofibers by CO disproportionation on ultrafine Fe 3 O 4
Author(s) -
Lu Wenxin,
Sui Zhijun,
Zhou Jinghong,
Li Ping,
Zhou Xinggui,
Chen De
Publication year - 2009
Publication title -
asia‐pacific journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.348
H-Index - 35
eISSN - 1932-2143
pISSN - 1932-2135
DOI - 10.1002/apj.295
Subject(s) - disproportionation , catalysis , carbon nanofiber , chemical engineering , hydrogen , dissociation (chemistry) , materials science , carbon fibers , chemistry , composite material , organic chemistry , composite number , engineering
Carbon nanofibers (CNFs) are grown by catalytic CO disproportionation over ultrafine Fe 3 O 4 catalyst at a hydrogen concentration of 0–29.17%, and the time‐depending rates of CNFs growth are continuously monitored and the morphologies of the as‐synthesized CNFs are analyzed. Increasing H 2 concentration will lower CO dissociation energy and assist catalyst reconstruction so as to shorten the induction period and increase the growth rate of CNFs, but it will also increase the rate of catalyst deactivation because carbon hydrogasification is not possible and carbon diffusion in the catalyst particle is rate limiting. As a result of H 2 ‐induced catalyst reconstruction and carbon deposition, the morphology of the CNFs changes from twisty to helical and to straight and becomes less entangled when the H 2 concentration is increased. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd.