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Role of graphene oxide/yttrium oxide nanocomposites as a cathode material for natural dye‐sensitized solar cell applications
Author(s) -
Shanmugapriya T.,
Balavijayalakshmi J.
Publication year - 2020
Publication title -
asia‐pacific journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.348
H-Index - 35
eISSN - 1932-2143
pISSN - 1932-2135
DOI - 10.1002/apj.2598
Subject(s) - graphene , materials science , oxide , scanning electron microscope , nanocomposite , fourier transform infrared spectroscopy , raman spectroscopy , chemical engineering , analytical chemistry (journal) , nuclear chemistry , nanotechnology , chemistry , composite material , optics , organic chemistry , physics , engineering , metallurgy
Natural dye‐sensitized solar cells (DSSCs) are becoming promising candidates for replacing synthetic dyes. Graphene oxide is prepared from natural graphite flakes by modified Hummers method. A novel graphene oxide/yttrium oxide (GO/Y 2 O 3 ) nanocomposites are prepared by chemical precipitation method. The different concentration of (5:1, 5:2, and 5:3) of yttrium oxide nanoparticles exaggerated on the surface of graphene oxide nanosheets. The prepared nanocomposites are characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), high‐resolution transmission electron microscopy (HR‐TEM), energy‐dispersive X‐ray spectroscopy (EDAX), Fourier transform infrared spectroscopy (FT‐IR), Raman scattering spectroscopy and ultraviolet–visible (UV–vis) absorption spectroscopy. The XRD analysis showed that the crystallite size of the GO/Y 2 O 3 (5:1, 5:2, and 5:3) is found to be around 23, 25.2, and 26.92 nm. Field emission scanning electron microscopy (FE‐SEM) revealed that the flakes like shaped yttrium oxide nanoparticles are uniformly dispersed on the surface of GO sheets. The UV–vis studies showed that the prepared Jasminoum grandiflorum L (JG) dye belongs to chlorophyll group with the absorption of 4.2 eV. The electrochemical activity of the prepared nanocomposites is investigated by cyclic voltammetry (CV) technique. The power conversion efficiency of prepared sandwich type DSSCs (5:3) is found to be 1.67%.