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Fabrication and analysis of palmitic acid–decanoic acid@Ce–Eu/TiO 2 composite as a building material for regulating indoor environment
Author(s) -
Zong Zhifang,
Chen Depeng,
Zhao Chunxiao,
Dong Wei,
Tang Gang,
Zhang Hao,
Zhu Xiujuan
Publication year - 2020
Publication title -
asia‐pacific journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.348
H-Index - 35
eISSN - 1932-2143
pISSN - 1932-2135
DOI - 10.1002/apj.2575
Subject(s) - materials science , photocatalysis , thermogravimetric analysis , chemical engineering , scanning electron microscope , mesoporous material , nuclear chemistry , composite material , chemistry , organic chemistry , engineering , catalysis
Abstract Novel palmitic acid–decanoic acid@Ce–Eu/TiO 2 (PA–DA@Ce–Eu/TiO 2 ) microspheres with high photocatalysis–thermal–humidity collaborative performance were prepared via a two‐step method. Ce and Eu were used for codoping to modify the TiO 2 hollow microspheres to enhance the photocatalytic properties. Furthermore, a eutectic phase change material (PA–DA) was combined with Ce–Eu/TiO 2 hollow microspheres to prepare PA–DA@Ce–Eu/TiO 2 microspheres. X‐ray diffraction and UV–VIS spectral analyses proved that Ce–Eu codoping enhanced the photocatalytic properties of the PA–DA@Ce–Eu/TiO 2 microspheres under solar light; the degradation rate to gaseous formaldehyde at low concentrations reached 54.98% after 5 h. The pore structure, particle size distribution, microstructure, and thermostability of the PA–DA@Ce–Eu/TiO 2 microspheres were determined using N 2 adsorption isotherms, laser scattering particle size distribution analysis, scanning electron microscopy, and thermogravimetric analysis, respectively. The results showed that the Ce–Eu/TiO 2 microspheres had a typical mesoporous structure, concentrated particle size distribution, and rough surface. The porous structure of the PA–DA@Ce–Eu/TiO 2 microspheres was conducive to adsorb/desorb moisture, which was recorded to be 0.0575 g/g at 43.16–75.29% relative humidity. The differential scanning calorimeter analysis showed that the phase transition temperature of the PA–DA@Ce–Eu/TiO 2 microspheres was 20–22°C and that the PA–DA@Ce–Eu/TiO 2 microspheres were stable at 35°C. After 300 thermal cycles, the heat storage capacity of the PA–DA@Ce–Eu/TiO 2 microspheres decreased by only 5%. Thus, we concluded that the PA–DA@Ce–Eu/TiO 2 microspheres can purify air and control indoor thermal and humidity environments simultaneously and hence can be used as functional building materials to adjust the indoor environment.