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High‐temperature char gasification of anthracite/petroleum coke: using biomass leachate as cheap‐effective additive
Author(s) -
Wei Juntao,
Ding Lu,
Gong Yan,
Guo Qinghua,
Wang Yifei,
Yu Guangsuo
Publication year - 2020
Publication title -
asia‐pacific journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.348
H-Index - 35
eISSN - 1932-2143
pISSN - 1932-2135
DOI - 10.1002/apj.2454
Subject(s) - char , pyrolysis , anthracite , chemistry , chemical engineering , reactivity (psychology) , kinetics , thermogravimetric analysis , biomass (ecology) , coke , waste management , materials science , organic chemistry , coal , geology , medicine , physics , alternative medicine , oceanography , pathology , quantum mechanics , engineering
Abstract Rice straw leachate (RSL) was employed as cheap‐effective biomass‐based additive for anthracite/petroleum coke (JM/PC) gasification. The influence of RSL on high‐temperature (1,000–1,300°C) char gasification reactivity and kinetics was analyzed by thermogravimetric analysis. The results demonstrate that for PC char, catalytic effect of RSL on its gasification reactivity existed within the whole temperature range and was initially weakened and then enhanced as gasification temperature increased (turning‐point temperature, 1,200°C). For JM char, as gasification temperature increased, the influencing form of RSL on its gasification reactivity was initially presented as the weakened catalytic effect and turned into the reduced inhibition effect within 1,200–1,300°C. These phenomena were mainly attributed to the concentration and activity variations of alkali/alkaline earth metal species derived from RSL during JM/PC char gasification at different temperatures. Kinetics analysis based on conventional models indicates that random pore model (RPM) was more suitable to describe char gasification. Moreover, RSL additive could reduce the activation energy of JM char and PC char gasification by 12.71 and 43.39 kJ·mol −1 , respectively, which implied that RSL help to improve char gasification kinetics and exhibited more positive effect on PC char. Kinetics analysis based on free‐model method verified the reliability and accuracy of RPM.