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Effect of granulating characteristics on harmless disposal of waste selective catalytic reduction catalyst in iron ore sintering process
Author(s) -
Zhou Hao,
Ma Pengnan,
Zuo Yuhang,
Wang Jiankang,
lv Laiquan,
Meng Hanxiao,
Cen Kefa
Publication year - 2020
Publication title -
asia‐pacific journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.348
H-Index - 35
eISSN - 1932-2143
pISSN - 1932-2135
DOI - 10.1002/apj.2428
Subject(s) - sintering , moisture , materials science , porosity , catalysis , iron ore , microstructure , metallurgy , waste management , composite material , chemistry , biochemistry , engineering
Abstract The harmless treatment of waste selective catalytic reduction catalyst has become a thorny problem. In this investigation, a new method of harmless disposal of waste catalyst by utilizing iron ore sintering process is proposed, and the effect of granulating characteristics is studied. Results show that better bed permeability, shorter sintering time, and faster flame front speed could be characterized by applying higher granulating moisture. Sinter mineral and microstructure research found that wider distribution of skeleton‐crystal hematite while less calcium ferrite could be observed at higher granulating moisture. The porosity of sinter increases from 30.82% for granulating moisture 6.0% to 36.54% for granulating moisture 7.5% while the circle factor of pores decreases. Sinter index research results indicate that both tumbler index and yield have a descended trend whereas flame front speed increases with higher granulating moisture added. Productivity first increases then drops with increasing granulating moisture. Finally, a comprehensive index is used to evaluate the influence of granulating characteristics on sintering process, which first increases from 100 to 121 as granulating moisture increases from 6% to 6.5% then drops to 70.8 when granulating moisture further increases to 7.5%. The granulating moisture of 6.5% is recommended in present study.