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Potential Vegetable‐Based Diesel Fuels from Perkin Condensation of Furfuraldehyde and Fatty Acid Anhydrides
Author(s) -
Baldwin Lawrence C.,
Davis Matthew C.,
Hughes Alicia M.,
Lupton David V.
Publication year - 2019
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1002/aocs.12210
Subject(s) - cetane number , flash point , diesel fuel , heat of combustion , freezing point , chemistry , pour point , biofuel , organic chemistry , melting point , biodiesel , acid value , capric acid , pulp and paper industry , waste management , combustion , fatty acid , lauric acid , thermodynamics , catalysis , physics , engineering , biochemistry
Domestically produced biofuels may help to reduce dependence on imported oil for powering transportation and infrastructure in the future. In this report, we reacted medium‐chain and long‐chain fatty anhydrides (capric, caprylic, lauric, and palmitic) with furfuraldehyde by the Perkin condensation to produce 2‐ n ‐alkenylfurans. In the second step, the 2‐ n ‐alkenylfurans were hydrogenated to form 2‐ n ‐alkyltetrahydrofurans. Basic fuel property testing (melting point, density, kinematic viscosity, derived cetane number, and calorific value) of the 2‐ n ‐alkyltetrahydrofurans indicates they are potentially useful as fuels for diesel engines. The mixture composed of 2‐octyl‐ and 2‐decyltetrahydrofuran had the best combination of fuel properties including a low melting point (−39 °C), high cetane number (63.1), high flash point (98.2 °C), and low viscosity (2.26 mm 2 s −1 , 40 °C), which compares favorably with specifications for diesel #2 and biodiesel.