Premium
Luminescence characteristics and X‐ray crystal structure of [Cd(bipy) 3 ][PF 6 ] 2 (bipy = 2,2′‐bipyridine)
Author(s) -
Kundu Nabanita,
Mandal Debdas,
Chaudhury Muktimoy,
Tiekink Edward R. T.
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.996
Subject(s) - dication , chemistry , photoluminescence , octahedron , acetonitrile , luminescence , crystallography , crystal structure , quantum yield , crystal (programming language) , x ray crystallography , 2,2' bipyridine , yield (engineering) , molecule , optics , diffraction , physics , organic chemistry , fluorescence , programming language , computer science , thermodynamics
The photoluminescence characteristics of the [Cd(bipy) 3 ][PF 6 ] 2 complex are reported. A moderately large quantum yield (φ) of 1.07 × 10 −2 is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by CH···π and CH···F interactions. Copyright © 2005 John Wiley & Sons, Ltd.