Luminescence characteristics and X‐ray crystal structure of [Cd(bipy) 3 ][PF 6 ] 2  (bipy = 2,2′‐bipyridine) | Zendy

Kundu Nabanita | Zendy; Mandal Debdas | Zendy; Chaudhury Muktimoy | Zendy; Tiekink Edward R. T. | Zendy

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Luminescence characteristics and X‐ray crystal structure of [Cd(bipy) 3 ][PF 6 ] 2 (bipy = 2,2′‐bipyridine)

Author(s) -

Kundu Nabanita,

Mandal Debdas,

Chaudhury Muktimoy,

Tiekink Edward R. T.

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.996

Subject(s) - dication , chemistry , photoluminescence , octahedron , acetonitrile , luminescence , crystallography , crystal structure , quantum yield , crystal (programming language) , x ray crystallography , 2,2' bipyridine , yield (engineering) , molecule , optics , diffraction , physics , organic chemistry , fluorescence , programming language , computer science , thermodynamics

The photoluminescence characteristics of the [Cd(bipy) 3 ][PF 6 ] 2 complex are reported. A moderately large quantum yield (φ) of 1.07 × 10 −2 is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by CH···π and CH···F interactions. Copyright © 2005 John Wiley & Sons, Ltd.

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