Short communication: An alternative and effective catalyst in the stereo‐specific reaction of  Z ‐1‐aryl‐1‐stannyl‐2‐silylethenes with allyl bromide | Zendy

Nakano Taichi | Zendy; Kawai Kenji | Zendy; Endoh Takanori | Zendy; Osada Shintaro | Zendy; Miyamoto Takashi | Zendy

Premium

Short communication: An alternative and effective catalyst in the stereo‐specific reaction of Z ‐1‐aryl‐1‐stannyl‐2‐silylethenes with allyl bromide

Author(s) -

Nakano Taichi,

Kawai Kenji,

Endoh Takanori,

Osada Shintaro,

Miyamoto Takashi

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.957

Subject(s) - chemistry , aryl , bromide , iodide , catalysis , trimethylsilyl , medicinal chemistry , allyl bromide , dimethylformamide , organic chemistry , polymer chemistry , alkyl , solvent

The Pd(dba) 2 ‐catalyzed reaction of Z ‐1‐aryl‐1‐(tributylstannyl)‐2‐(trimethylsilyl)ethenes with allyl bromide in the presence of copper(I) iodide is reported for the first time. The reaction in the presence of 0.5 mol% Pd(dba) 2 and 8 mol% CuI in dimethylformamide takes place at room temperature to give E ‐2‐aryl‐1‐(trimethylsilyl)penta‐1,4‐dienes exclusively in isolated yields of 62–99%. A putative reaction mechanism is proposed. Copyright © 2005 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research