Germanium carboxylates: the first X‐ray diffraction study of germanium(II) dicarboxylate and germanium(IV) tetracarboxylate | Zendy

Khrustalev Victor N. | Zendy; Portnyagin Ivan A. | Zendy; Zemlyansky Nikolay N. | Zendy; Borisova Irina V. | Zendy; Ustynyuk Yuri A. | Zendy; Antipin Mikhail Yu. | Zendy; Nechaev Mikhail S. | Zendy; West Robert | Zendy

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Germanium carboxylates: the first X‐ray diffraction study of germanium(II) dicarboxylate and germanium(IV) tetracarboxylate

Author(s) -

Khrustalev Victor N.,

Portnyagin Ivan A.,

Zemlyansky Nikolay N.,

Borisova Irina V.,

Ustynyuk Yuri A.,

Antipin Mikhail Yu.,

Nechaev Mikhail S.,

West Robert

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.877

Subject(s) - germanium , chemistry , germanium compounds , x ray crystallography , diffraction , crystallography , organic chemistry , optics , physics , silicon

Germanium(II) dipropionate (1) has been synthesized and its crystal structure, as well as that of germanium(IV) tetrapropionate (2), has been determined. By contrast to monomeric 2 with monodentate propionate ligands, compound 1 is associated, forming a cyclotetramer [Ge(O 2 CEt) 2 ] 4 (1a) via intermolecular dative CO → Ge interactions. Copyright © 2005 John Wiley & Sons, Ltd.

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