Three‐coordinate divalent Group 14 element derivatives and related compounds | Zendy

Saur Isabelle | Zendy; Garcia Alonso Sonia | Zendy; Barrau Jacques | Zendy

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Three‐coordinate divalent Group 14 element derivatives and related compounds

Author(s) -

Saur Isabelle,

Garcia Alonso Sonia,

Barrau Jacques

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.876

Subject(s) - chemistry , stannane , germanium , main group element , germane , divalent , carbon group , tin , transition metal , cationic polymerization , ligand (biochemistry) , group (periodic table) , metal , stereochemistry , metalation , divalent metal , crystallography , organic chemistry , catalysis , silicon , biochemistry , receptor

This review describes recent work on the synthesis, spectroscopic analysis, structures and investigation of chemical behaviours of new subvalent germanium and tin compounds supported by the β‐diketiminato ligand L 2 (L 2 = NPhC(Me)CHC(Me)NPh), namely the divalent species L 2 (X)M, the germane and stannane chalcogenones L 2 (X)MY, the heavier Group 14 element transition‐metal complexes L 2 (X)MM′(CO) n and the cationic germanium–transition‐metal complexes [L 2 Ge + M′(CO) n ]. Copyright © 2005 John Wiley & Sons, Ltd.

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