Synthesis and photochemical reactions of 1,2,7‐chalcogenadistannacycloheptanes | Zendy

Saito Masaichi | Zendy; Iso Kaori | Zendy; Yamada Katsuhiko | Zendy; Nakano Susumu | Zendy; Yoshioka Michikazu | Zendy

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Synthesis and photochemical reactions of 1,2,7‐chalcogenadistannacycloheptanes

Author(s) -

Saito Masaichi,

Iso Kaori,

Yamada Katsuhiko,

Nakano Susumu,

Yoshioka Michikazu

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.870

Subject(s) - chemistry , mercury vapor lamp , mercury (programming language) , irradiation , reagent , photochemistry , butane , high pressure , organic chemistry , catalysis , physics , optoelectronics , computer science , nuclear physics , programming language , engineering physics , engineering

1,2,7‐Chalcogenadistannacycloheptanes were synthesized by the reactions of 1,4‐bis(bromostannyl) butane with appropriate chalcogenation reagents. Irradiation of the 1,2,7‐thiadistannacycloheptane with a low‐pressure mercury lamp (254 nm) gave 1,3,5,2,4,6‐trithiatristannin. Irradiation of 1,3,5,2,4,6‐trithiatristannin with a low‐pressure mercury lamp in the presence of either cyclotrisiloxane or 2,3‐dimethyl‐1,3‐butadiene gave a complex mixture. Copyright © 2005 John Wiley & Sons, Ltd.

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