Reaction of phenyltrifluorosilane with 8‐hydroxy‐ or 8‐mercapto‐quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon | Zendy

Voronkov Mikhail G. | Zendy; Trofimova Olga M. | Zendy; Chernov Nikolai F. | Zendy; Albanov Aleksandr I. | Zendy; Chipanii. | Zendy; Grebneva Ekaterina A. | Zendy

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Reaction of phenyltrifluorosilane with 8‐hydroxy‐ or 8‐mercapto‐quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon

Author(s) -

Voronkov Mikhail G.,

Trofimova Olga M.,

Chernov Nikolai F.,

Albanov Aleksandr I.,

Chipanii.,

Grebneva Ekaterina A.

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.861

Subject(s) - chemistry , quinoline , intramolecular force , trimethylsilyl , silanes , silicon , medicinal chemistry , stereochemistry , combinatorial chemistry , organic chemistry , silane

The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC 9 H 6 YH (Y: O, 1a ; S, 1b ) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. The (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure. Copyright © 2005 John Wiley & Sons, Ltd.

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