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Reaction of phenyltrifluorosilane with 8‐hydroxy‐ or 8‐mercapto‐quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon
Author(s) -
Voronkov Mikhail G.,
Trofimova Olga M.,
Chernov Nikolai F.,
Albanov Aleksandr I.,
Chipanii.,
Grebneva Ekaterina A.
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.861
Subject(s) - chemistry , quinoline , intramolecular force , trimethylsilyl , silanes , silicon , medicinal chemistry , stereochemistry , combinatorial chemistry , organic chemistry , silane
The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC 9 H 6 YH (Y: O, 1a ; S, 1b ) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. The (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure. Copyright © 2005 John Wiley & Sons, Ltd.