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Crystallographic report: Dichloro[bis(1‐methylimidazole‐2)disulfide]zinc(II)
Author(s) -
Matsunaga Yuki,
Fujisawa Kiyoshi,
Amir Nagina,
Miyashita Yoshitaro,
Okamoto Kenichi
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.832
Subject(s) - chemistry , disulfide bond , zinc , tetrahedron , crystallography , center (category theory) , stereochemistry , organic chemistry , biochemistry
The Zn center in [ZnCl 2 (L‐S‐S‐L)], where L‐S‐S‐L = bis(1‐methylimidazole‐2)disulfide, adopts a tetrahedral configuration defined by two Cl atoms and two N atoms from L‐S‐S‐L, which was obtained by in situ oxidation of 1‐methylimidazole‐2‐thione. Copyright © 2005 John Wiley & Sons, Ltd.