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The germanium(II) ate complex [Ph 3 P i Pr][Ge(OCOMe) 3 ]: the first structurally characterized compound containing a discrete [E 14(II) O 3 ] (−) (E 14(II) = Si, Ge, Sn or Pb) anion
Author(s) -
Khrustalev Victor N.,
Antipin Mikhail Yu.,
Zemlyansky Nikolay N.,
Borisova Irina V.,
Ustynyuk Yuri A.,
Lunin Valery V.,
Izod Keith
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.825
Subject(s) - germanium , chemistry , denticity , ion , crystallography , trigonal crystal system , x ray crystallography , stereochemistry , germanium compounds , crystal structure , diffraction , silicon , organic chemistry , optics , physics
An X‐ray diffraction study reveals an unusual structure of the new thermally stable germanium(II) ate complex [Ph 3 P i Pr][Ge(OAc) 3 ] (4) containing a discrete [Ge(OAc) 3 ] (−) anion containing monodentate acetate ligands with a trigonal pyramidal germanium centre. Copyright © 2005 John Wiley & Sons, Ltd.