The germanium(II) ate complex [Ph 3 P i Pr][Ge(OCOMe) 3 ]: the first structurally characterized compound containing a discrete [E 14(II) O 3 ] (−)  (E 14(II)  = Si, Ge, Sn or Pb) anion | Zendy

Khrustalev Victor N. | Zendy; Antipin Mikhail Yu. | Zendy; Zemlyansky Nikolay N. | Zendy; Borisova Irina V. | Zendy; Ustynyuk Yuri A. | Zendy; Lunin Valery V. | Zendy; Izod Keith | Zendy

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The germanium(II) ate complex [Ph 3 P i Pr][Ge(OCOMe) 3 ]: the first structurally characterized compound containing a discrete [E 14(II) O 3 ] (−) (E 14(II) = Si, Ge, Sn or Pb) anion

Author(s) -

Khrustalev Victor N.,

Antipin Mikhail Yu.,

Zemlyansky Nikolay N.,

Borisova Irina V.,

Ustynyuk Yuri A.,

Lunin Valery V.,

Izod Keith

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.825

Subject(s) - germanium , chemistry , denticity , ion , crystallography , trigonal crystal system , x ray crystallography , stereochemistry , germanium compounds , crystal structure , diffraction , silicon , organic chemistry , optics , physics

An X‐ray diffraction study reveals an unusual structure of the new thermally stable germanium(II) ate complex [Ph 3 P i Pr][Ge(OAc) 3 ] (4) containing a discrete [Ge(OAc) 3 ] (−) anion containing monodentate acetate ligands with a trigonal pyramidal germanium centre. Copyright © 2005 John Wiley & Sons, Ltd.

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